Determination of polymer–polymer interaction parameters using inverse gas chromatography

A modified method is discussed that is based on Farooque and Deshpande's method to obtain polymer–polymer interaction parameters using inverse gas chromatography (IGC) data. In the Farooque and Deshpande method, the ratio of the difference of probe–polymer interaction parameters between two polymers and the probe volume [(χ₁₂ ? χ₁₃)/V₁] is used as the abscissa. In the modified method, the ratio [(?₂χ₁₂ + ?₃χ₁₃)/V₁] is used as the abscissa. Experimental data previously reported for a poly(?‐caprolactone)‐polyepichlorohydrin (PCL/PECH) blend and a poly(ethyl acrylate)‐poly(vinyl propionate) (PEA/PVPr) blend are analyzed. It is found that the slopes obtained by the new method had smaller deviations from the theoretical values than the Farooque and Deshpande method. The standard deviations of both slopes and intercepts obtained from the new method are also smaller. Using the new method, the polymer–polymer interaction parameters obtained from the intercept are negative numbers for the PCL/PECH system and very small positive numbers for PEA/PVPr. Explanations are given for the probe and concentration dependency of the polymer–polymer interaction parameters that are generally observed in IGC studies. A new method for selecting the best probe for calculating the interaction parameter is discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 671–680, 2003     

用Java 3D技术开发基于网络的分子模拟可视化系统

分子模拟的可视化在分子模拟系统中具有重要的现实意义,本文在分析了网络环境下Java3D的图形处理优势之后,就开发基于网络环境的分子模拟可视化系统中的三维图形的结构表示、生成、显示、控制以及模拟结果的动态显示等问题进行了探讨,这些方法已成功地用于基于网络环境的分子模拟可视化系统。     

结构-波浪-海床耦合系统中大圆筒结构的波压力响应

以沉入式大圆筒结构为对象，通过设计随机波浪水槽实验，测取了在单筒和连续筒两种结构型式、两种沉入深度和两种波谱输入下结构表面的动波压力分布。波面高度以及波压力历程均在领域进行分析。通过计算结构表面沿高程和沿环向的波压力谱及波压力传递函数，将单筒实测结果与基于线性绕射理论的解析解进行了比较，同时也详细对比了两种结构型式下的实测结果。文中汇报了在研究中获得的新发现及进行的相应分析，特别是在结构——波浪——海床动力相互作用下对波压力响应机理以及针对连续筒的研究，可为工程应用提供有价值的参考。     

Simulation by Slepian method of plastic displacements of Gaussian process excited multistory shear frame

The object of study is a stationary Gaussian white noise excited multi-degree-of-freedom (MDOF) linear elastic, ideal plastic, linearly damped, statically determinate oscillator with several potential elements of ideal plastic yielding. Specifically the study is exemplified for a plane multistory shear frame with rigid traverses where all the connecting columns except the columns in one or more of the bottom floors have finite symmetrical yield limits. The white noise excitation acts on the mass of the first floor making the movement of the elastic bottom floors simulate a ground motion that interacts with the structure above the bottom floors. The method of study is so-called Slepian model simulation and is in principle the same for other statically determinate MDOF elasto-plastic oscillators of the considered type. The method is fast as compared to direct simulation and provides results that give good insight in the behavior of the plastic displacement response process.     

Finite elements in the analysis of pressure vessels and piping-a bibliography (1976–1996)

The paper gives a bibliographical review of the finite element methods (FEMs) applied for the analysis of pressure vessel structures/components and piping from the theoretical as well as practical points of view. The range of applications of FEMs in this area is wide and cannot be presented in a single paper; therefore the aim of this review is to give the reader an encyclopaedic view of the differnt possibilities that exist today for the finite element analysis in the fields of pressure vessels and piping. The bibliography at the end of the paper contains approximately 1900 references to papers, conference proceedings and theses/dissertations on the subject that were published in 1976–1996. These are classified in the following categories: linear and non-linear, static and dynamic, stress and deflection analysis; stability problems; thermal problems; fracture mechanics problems; contact problems; fluid-structure interaction problems; manufacturing of pipes and tubes; welded pipes and pressure vessel components; development of special finite elements for pressure vessels and pipes; finite element software; and other topics. Also finite element software, general purpose and special purpose codes, used for the analysis of pressure vessels and pipes are briefly discussed and presented.     

On integral equation approaches to the mechanics of fibre-crack interaction

The paper examines the problem of a penny-shaped crack which is formed by the development of a crack in both the fibre and the matrix of a composite consisting of an isolated elastic fibre located in an elastic matrix of infinite extent. The composite region is subjected to a uniform strain field in the direction of the fibre. The paper presents two integral-equation based approaches for the analysis of the problem. The first approach considers the formulation of the complete integral equations governing the associated elasticity problem for a two material region. The second approach considers the boundary integral equation formulation of the problem. Both methods entail the numerical solution of the governing integral equations. The solutions to these integral equations are used to evaluate the stress intensity factor at the boundary of the penny-shaped crack.     

Locked discrete event systems: How to model and how to unlock

To model qualitative aspects of discrete event systems, i.e., the order of the events is of sole importance, we use a triple consisting of the set of all possible events (the alphabet), the set of all behavior (possible strings of events), and the set of all tasks (completed behavior). We use this view to model synchronous as well as asynchronous connection of systems. Moreover, it is easy to define notions like deadlock and livelock in this view. We give a method to construct a second system that, in connection with the original system, gets rid of its deadlock and/or livelock. A state-space representation is introduced. In this representation computations can be done effectively.     

聚电解质溶液分子热力学模型

<正>链状聚电解质由于是长链大分子又有很高的电荷密度,其溶液即使在极低的浓度下仍具有很强的负偏差,与Debye-Huckel理论预测的结果相去甚远。工程上使用的Manning模型认为聚离子的电荷密度有一临界值,当超过临界值时,反离子即凝聚在聚离子表面使其实际电荷密度降至临界值。Nagvekar等在该模型的基础上引入NRTL方程,以计及短程相互作用的贡献。Manning等的方法虽然有一定的物理意义,但临界值的确定缺乏可靠的根据。     

Structure for user-oriented dialogues in computer-aided telephony

Members of The Speech Project, at Oxford Brookes University, have been experimenting with alternative structures for ‘goal-seeking’ dialogues. A dialogue prototyping system has been developed that can instantiate different dialogue structures kept on file. These become active after being installed using dynamic data structures. Input is achieved using speech recognition for a small range of words, and output is in the form of pre-recorded speech messages. The dialogues thus created employ a new approach, and replace the usual menustructure with a simpler question-answer process.

The nature of dialogues using computer aided telephony is analysed, and then the work done by members of The Speech Project on an alternative approach using a simpler dialogue structure is described.     

Investigation of the Interaction of Sodium Chloride and Two Amino Sulfonic Acids,HEPES and MOPSO,by EMF Measurements

Ionic interactions in the two systems NaCl-HEPES (N-2-hydroxyethylpiperazine-N′-2-ethanesulfonic acid) and NaCl-MOPSO (3-(N-Morpholino)-2-hydroxypropanesulfonic acid) have been studied in terms of their mutual influence on the respective activity coefficients of each component. Activity coefficients for each component of the two systems and for corresponding buffers are calculated from emf measurements of solutions containing NaCl, the aminosulfonic acid, and its conjugate base in a NalSE/solution/AgCl-Ag cell at 5, 15, 25, and 37 °C.